典型文献
Structure characteristics and microwave dielectric properties of Pr2(Zr1-xTix)3(MoO4)9 solid solution ceramic with a stable temperature coefficient
文献摘要:
Pr2(Zr1-xTix)3(MoO4)9(x=0.1-1.0)ceramics were prepared via a conventional solid-state method,the dependence of crystal structure and bond characteristics on microwave dielectric properties was investi-gated systemically.The X-ray diffraction patterns indicated that the single-phase Pr2Zr3(MoO4)9 structure was formed in all the specimens.As the Ti4+content increased,the lattice volume gradually decreased,which was ascribed to the fact that the ionic radius of Ti4+was smaller than that of Zr4+.Notably,out-standing microwave dielectric properties with εr of 10.73-16.35,Qf values of 80,696-18,726 GHz and minor rf values-14.1--2.6 ppm/℃were achieved in Pr2(Zr1-xTix)3(MoO4)9 ceramics.The εr increased with the rising x values,which was associated with the increase of α/Vm values.The decreasing Qf was affected by the decline of lattice energy of[Zr/TiO6]octahedral.The τf value was dominated by[Zr/TiO6]octahedral distortion,Mo-O bond energy,bond strength and B-site bond valence.Furthermore,infrared reflection spectra suggested that the properties were mainly caused by the absorption of phonon,and the dielectric loss could be further reduced by optimizing the experimental process.
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中图分类号:
作者姓名:
Huanrong Tian;Jinjie Zheng;Lintao Liu;Haitao Wu;Hideo Kimura;Yizhong Lu;Zhenxing Yue
作者机构:
School of Environmental and Material Engineering,Yantai University,Yantai 264005,China;School of Materials Science and Engineering,University of Jinan,Jinan 250022,China;State Key Laboratory of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University,Beijing 100084,China
文献出处:
引用格式:
[1]Huanrong Tian;Jinjie Zheng;Lintao Liu;Haitao Wu;Hideo Kimura;Yizhong Lu;Zhenxing Yue-.Structure characteristics and microwave dielectric properties of Pr2(Zr1-xTix)3(MoO4)9 solid solution ceramic with a stable temperature coefficient)[J].材料科学技术(英文版),2022(21):121-129
A类:
Pr2,xTix,Pr2Zr3,Ti4+content,Ti4+was
B类:
Structure,characteristics,microwave,dielectric,properties,Zr1,MoO4,solid,solution,stable,temperature,coefficient,ceramics,were,prepared,via,conventional,state,method,dependence,crystal,structure,bond,investi,gated,systemically,ray,diffraction,patterns,indicated,that,single,phase,formed,specimens,increased,lattice,volume,gradually,decreased,which,ascribed,fact,ionic,radius,smaller,than,Zr4+,Notably,out,standing,Qf,values,GHz,minor,rf,ppm,achieved,rising,associated,Vm,decreasing,affected,by,decline,energy,TiO6,octahedral,dominated,distortion,strength,site,valence,Furthermore,infrared,reflection,spectra,suggested,mainly,caused,absorption,phonon,loss,could,further,reduced,optimizing,experimental,process
AB值:
0.501966
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