典型文献
Energy band engineering of Bi2O2.33-CdS direct Z-scheme heterojunction for enhanced photocatalytic reduction of CO2
文献摘要:
In this work,a Bi2O2.33-CdS direct Z-scheme heterojunction was fabricated based on energy band en-gineering.The Bi2O2.33 core nanoflakes were first synthesized by electrodeposition which was followed by an annealing process to fabricate this heterojunction.Then the CdS shell was deposited on Bi2O2.33 nanoflakes utilizing the solution method,during which a suitable concentration of CdCl2 solution was used for forming a homogeneous and continuous integrated CdS shell.A space charge region and an in-ternal electric field from CdS(+)to Bi2O2.33(-),which drove a direct Z-scheme charge transfer process,were formed at the interface.The Bi2O2.33-CdS exhibited excellent photocatalytic performance for CO2 reduction mainly attributed to the satisfactory photoinduced charge separation and transport efficiency in the direct Z-scheme heterojunction.The photocatalytic CO2 reduction ability of Bi2O2.33-CdS was sig-nificantly enhanced compared with single Bi2O2.33 or CdS,with a CO yield rate of ca.2.9 μmol/(cm2 h)under a 300 W Xe lamp.The reduction of CO2 to CO demonstrated 94.0%selectivity.
文献关键词:
中图分类号:
作者姓名:
Guojing Wang;Zhiwei Tang;Jing Wang;Shasha Lv;Yunjie Xiang;Feng Li;Chong Liu
作者机构:
School of Physical Science and Technology,Lanzhou University,Lanzhou 730000,China;Department of Electronic Materials Science and Engineering,School of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,China;Key Laboratory of Beam Technology and Material Modification,Ministry of Education,College of Nuclear Science and Technology,Beijing Normal University,Beijing 100875,China;School of Materials and Energy,Southwest University,Chongqing 404100,China
文献出处:
引用格式:
[1]Guojing Wang;Zhiwei Tang;Jing Wang;Shasha Lv;Yunjie Xiang;Feng Li;Chong Liu-.Energy band engineering of Bi2O2.33-CdS direct Z-scheme heterojunction for enhanced photocatalytic reduction of CO2)[J].材料科学技术(英文版),2022(16):17-27
A类:
gineering
B类:
Energy,band,engineering,Bi2O2,CdS,direct,scheme,heterojunction,enhanced,photocatalytic,reduction,In,this,work,was,fabricated,energy,core,nanoflakes,were,first,synthesized,by,electrodeposition,which,followed,annealing,process,Then,shell,deposited,utilizing,solution,method,during,suitable,concentration,CdCl2,used,forming,homogeneous,continuous,integrated,space,charge,region,ternal,electric,field,from,drove,transfer,formed,interface,exhibited,excellent,performance,mainly,attributed,satisfactory,photoinduced,separation,transport,efficiency,ability,sig,nificantly,compared,single,yield,under,Xe,lamp,demonstrated,selectivity
AB值:
0.4892
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