典型文献
Monodisperse micro-spherical Sr2-zMg1+yYzAl22-xO36∶xMn4+red phosphors
文献摘要:
With narrow red photoluminescence(PL)bands,tetravalent Mn4+doped phosphors show promising prospect in commercial application to effectively expand color gamut of phosphor converted LED dis-plays.Here,we report a type of Sr2-zMg1+yYzAl22-xO36∶xMn4+phosphors with regular cage-like micro-spherical morphologies.The micron size spherical precursors were synthesized with a propylene oxide(PO)driven fast sol-gel method.The cage-like spherical morphology is beneficial to efficiently trapping much incident light to enhance the PL of the phosphors.Being calcined at 1300℃,Sr2MgAl21.978O36∶0.022Mn4+only exhibits the internal quantum efficiency(IQE)of 24.91%.With the Mg2+-Mn4+codoping and Y3+/Sr2+substituting strategies,to fulfill charge balance and produce John-Teller distortion,IQE of Sr2-zMg1+yYzAl22-xO36∶xMn4+can be further improved up to 36.45%.The CIE color coordinates of Sr2-zMg1+yYzAl22-xO36∶xMn4+under near ultraviolet excitation can be stably fixed to(0.723,0.227)at deep red region.It thus finds a potential application as pc-LED display with much broader color gamut than that of the NTSC standard.Therefore,Sr2-zMg1+yYzAl22-xO36∶xMn4+micron size spheres can be employed as promising red phosphors for high performance LED displays.
文献关键词:
中图分类号:
作者姓名:
Jiannan Jia;Mengting He;Jun Wan;Yuting Zhang;Hai Guo;Xianping Fan;Xusheng Qiao;Shiguo Chen
作者机构:
Department of Physics,Zhejiang Normal University,Jinhua 321004,China;State Key Laboratory of Silicon Materials&School of Materials Science and Engineering,Zhejiang University,Hangzhou 310027,China;Shenzhen Key Laboratory of Polymer Science and Technology,College of Materials Science and Engineering,Shenzhen University,Shenzhen 518055,China
文献出处:
引用格式:
[1]Jiannan Jia;Mengting He;Jun Wan;Yuting Zhang;Hai Guo;Xianping Fan;Xusheng Qiao;Shiguo Chen-.Monodisperse micro-spherical Sr2-zMg1+yYzAl22-xO36∶xMn4+red phosphors)[J].稀土学报(英文版),2022(04):526-533
A类:
zMg1+yYzAl22,xO36,xMn4+red,Mn4+doped,xMn4+phosphors,Sr2MgAl21,978O36,022Mn4+only,IQE,Mn4+codoping,Sr2+substituting,xMn4+can,xMn4+under,xMn4+micron
B类:
Monodisperse,spherical,With,narrow,photoluminescence,PL,bands,tetravalent,show,promising,prospect,commercial,application,effectively,expand,color,gamut,converted,LED,Here,report,type,regular,cage,like,morphologies,precursors,were,synthesized,propylene,oxide,PO,driven,fast,sol,gel,method,morphology,beneficial,efficiently,trapping,much,incident,light,enhance,Being,calcined,exhibits,internal,quantum,efficiency,Mg2+,Y3+,strategies,fulfill,charge,balance,produce,John,Teller,distortion,further,improved,up,CIE,coordinates,near,ultraviolet,excitation,stably,fixed,deep,region,It,thus,finds,potential,pc,broader,than,that,NTSC,standard,Therefore,spheres,employed,high,performance,displays
AB值:
0.456846
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