典型文献
Ultra-small UiO-66-NH2 nanoparticles immobilized on g-C3N4 nanosheets for enhanced catalytic activity
文献摘要:
UiO-66-NH2,an important metal-organic framework,is usually synthesized by solvothermal method and the particle size is generally larger than 200 nm,which limits its catalytic applications in chemical reactions.It is very meaningful to produce UiO-66-NH2 nanoparticles with ultra-small size,but remains challenging.Herein,we synthesized UiO-66-NH2 nanoparticles in size of 8-15 nm that are immobilized on g-C3N4 nanosheets.Compared with the UiO-66-NH2 synthesized by the traditional solvothermal method(>200 nm),the ultra-small UiO-66-NH2 nanoparticles immobilized on g-C3N4 have more unsaturated coordination positions and increased Lewis acidity.Owing to these combined advantages,the ultra-small UiO-66-NH2 nanoparticles exhibit greatly improved catalytic activity for Meerwein-Ponndorf-Verley reaction than larger UiO-66-NH2 particles.
文献关键词:
中图分类号:
作者姓名:
Zhuizhui Su;Bingxing Zhang;Xiuyan Cheng;Fanyu Zhang;Qiang Wan;Lifei Liu;Xiuniang Tan;Dongxing Tan;Lirong Zheng;Jianling Zhang
作者机构:
Beijing National Laboratory for Molecular Sciences,CAS Key Laboratory of Colloid and Interface and Thermodynamics,CAS Research/Education Center for Excellence in Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing,100190,China;School of Chemical Sciences,University of Chinese Academy of Sciences,Physical Science Laboratory,Huairou National Comprehensive,Science Center,Beijing,100190,China;Beijing Synchrotron Radiation Facility(BSRF),Institute of High Energy Physics,Chinese Academy of Sciences,Beijing,100049,China
文献出处:
引用格式:
[1]Zhuizhui Su;Bingxing Zhang;Xiuyan Cheng;Fanyu Zhang;Qiang Wan;Lifei Liu;Xiuniang Tan;Dongxing Tan;Lirong Zheng;Jianling Zhang-.Ultra-small UiO-66-NH2 nanoparticles immobilized on g-C3N4 nanosheets for enhanced catalytic activity)[J].绿色能源与环境(英文),2022(03):512-518
A类:
Meerwein,Ponndorf,Verley
B类:
Ultra,small,UiO,NH2,nanoparticles,immobilized,C3N4,nanosheets,enhanced,catalytic,activity,important,metal,organic,framework,usually,synthesized,by,solvothermal,method,generally,larger,than,which,limits,applications,chemical,reactions,It,very,meaningful,produce,ultra,but,remains,challenging,Herein,that,Compared,traditional,have,more,unsaturated,coordination,positions,increased,Lewis,acidity,Owing,these,combined,advantages,exhibit,greatly,improved
AB值:
0.441414
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