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典型文献
Synergistic effect of NiⅡ and Co/FeⅢ in doped mixed-valence phosphonate for enhancing electrocatalytic oxygen evolution
文献摘要:
Metal organophosphonates have been explored in energy-related fields due to their high chemical and thermal stability as a type of uniformly precursor,but only few of pristine metal organophosphonate are directly used for oxygen evolution reaction(OER)catalysts.Here,a mixed-valence iron phosphonate(Fe3-ppat)has been constructed and applied to OER catalysis considered the potential active sites in pillars FeⅡ(-H2O)4(COO)2 and inorganic layers FeⅢ(μ2-OH)PO3.Specifically,isostructural trimetallic framework Fe1.7Co0.3Ni1.0-ppat possesses a mini-mum overpotential(291 mV),small Tafel slope(91.65 mV dec-1),and high stability up to 83 h.The enhanced catalytic performance could be mainly ascribed to the synergistic effect of NiⅡ equivalent occupancy in pillars and Co/FeⅢ in layers.
文献关键词:
作者姓名:
Juan-Juan Hou;Jian-Tao Yuan;Wei Zhang;Ying-Xia Wang;Xian-Ming Zhang
作者机构:
Key Laboratory of Magnetic Molecules and Magnetic Information Materials(Ministry of Education),School of Chemistry and Material Science,Shanxi Normal University,Linfen,041004,China
引用格式:
[1]Juan-Juan Hou;Jian-Tao Yuan;Wei Zhang;Ying-Xia Wang;Xian-Ming Zhang-.Synergistic effect of NiⅡ and Co/FeⅢ in doped mixed-valence phosphonate for enhancing electrocatalytic oxygen evolution)[J].绿色能源与环境(英文),2022(03):432-439
A类:
organophosphonates,organophosphonate,ppat
B类:
Synergistic,effect,doped,mixed,valence,enhancing,electrocatalytic,oxygen,evolution,Metal,have,been,explored,energy,related,fields,due,their,high,chemical,thermal,stability,type,uniformly,precursor,but,only,few,pristine,are,directly,used,reaction,OER,catalysts,Here,iron,Fe3,has,constructed,applied,catalysis,considered,active,sites,pillars,H2O,COO,inorganic,layers,PO3,Specifically,isostructural,trimetallic,framework,Fe1,7Co0,3Ni1,possesses,mini,mum,overpotential,mV,small,Tafel,slope,dec,enhanced,performance,could,mainly,ascribed,synergistic,equivalent,occupancy
AB值:
0.642361
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