It has been suggested that the carbonated mantle reflected by Mg-Zn isotopic anomalies of Cenozoic intraplate basalts from East Asia coincides with the stagnant West Pacific slab in the man- tle transition zone. However, the northern boundary of such carbonated domain beneath East Asia is uncertain. Late Mesozoic-Cenozoic intraplate basalts are widespread in far eastern Russia and thus provide an opportunity to examine this issue. Here we report major-trace element contents and Sr-Nd- Mg-Zn isotopic compositions for 9 Late Mesozoic-Cenozoic basaltic samples from the Khanka Block and Sikhote-Alin accretionary complex. They are characterized by large variations in SiO2 contents (41 wt.％ to 50 wt.％) and CaO/Al2O3 (0.50 to 0.97), enrichments of large-ion lithophile elements (LILE), positive Nb-Ta anomalies and strongly negative K, Pb, Zr, Hf, Ti, Y anomalies in primitive mantle-nor- malized trace element spider diagram. Furthermore, the rocks show good correlations of Ti/Ti* with Hf/Hf*, La/Yb, Fe/Mn and trace element contents (e. g., Nb). In addition, they have lighter Mg and heavier Zn isotope compositions than the BSE estimates, coupled with depleted Sr-Nd isotope composi- tions. These elemental and isotopic characteristics cannot be explained by alteration, magma differenti- ation or diffusion, but are consistent with the partial melting of carbonated peridotite. By and large, the Late Mesozoic-Cenozoic basalts from far eastern Russia bear very similar geochemical characteris- tics as those Na-series Cenozoic basalts from eastern China. The extended region of Mg-Zn isotopic anomalies is roughly coincident with the stagnant West Pacific slab beneath East Asia, and all of these alkali basalts can be generated from mantle sources hybridized by recycled Mg-carbonates from the Pacific slab stagnant in the mantle transition zone. We infer that (1) the carbonated big mantle wedge extends to the NE edge of the West Pacific slab and may have also appeared in the Late Mesozoic due to the effect of the Paleo-Pacific slab beneath this region, and (2) decarbonation of stagnant slabs in the mantle transition zone is a key mechanism for carbon outgassing from deep mantle to surface via intra- plate alkali melts.

Ronghua Cai;Shan Xu;Dmitri A.Ionov;Jian Huang;Sheng-Ao Liu;Shuguang Li;Jingao Liu

State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Beijing 100083,China;Géosciences Montpellier,Universitéde Montpellier,34095 Montpellier,France;CAS Key Laboratory of Crust-Mantle Materials and Environments,School of Earth and Space Sciences,University of Science and Technology of China,Hefei 230026,China

地球科学学刊（英文版）

[1]Ronghua Cai;Shan Xu;Dmitri A.Ionov;Jian Huang;Sheng-Ao Liu;Shuguang Li;Jingao Liu-.Carbonated Big Mantle Wedge Extending to the NE Edge of the Stagnant Pacific Slab:Constraints from Late Mesozoic-Cenozoic Basalts from Far Eastern Russia)[J].地球科学学刊（英文版）,2022(01):121-132

Carbonated,Stagnant,Khanka,Sikhote,Alin,decarbonation

Big,Mantle,Wedge,Extending,NE,Edge,Pacific,Slab,Constraints,from,Late,Mesozoic,Cenozoic,Basalts,Far,Eastern,Russia,It,has,been,suggested,that,carbonated,mantle,reflected,by,Mg,isotopic,anomalies,intraplate,basalts,Asia,coincides,stagnant,West,transition,zone,However,northern,boundary,such,domain,beneath,uncertain,widespread,far,eastern,thus,provide,opportunity,examine,this,issue,Here,report,major,trace,contents,Sr,Nd,compositions,basaltic,samples,Block,accretionary,complex,They,characterized,large,variations,SiO2,wt,CaO,Al2O3,enrichments,lithophile,elements,LILE,positive,Nb,Ta,strongly,negative,Pb,Zr,Hf,Ti,primitive,malized,spider,diagram,Furthermore,rocks,show,good,correlations,Yb,Mn,In,addition,they,have,lighter,heavier,isotope,than,BSE,estimates,coupled,depleted,These,elemental,characteristics,cannot,explained,alteration,magma,differenti,diffusion,but,consistent,partial,melting,peridotite,By,bear,very,similar,geochemical,those,Na,series,China,extended,region,roughly,coincident,all,these,alkali,generated,sources,hybridized,recycled,carbonates,infer,big,wedge,extends,may,also,appeared,due,effect,Paleo,slabs,key,mechanism,outgassing,deep,surface,via,melts

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