典型文献
Fmoc-protected amino acids as luminescent and circularly polarized luminescence materials based on charge transfer interaction
文献摘要：
Fluorenylmethyloxycarbonyl(Fmoc)-protected amino acids are effective building blocks in self-assembled architectures at hierarchical levels,which however show limited luminescent properties and chiroptical activities.Here we introduce a charge-transfer strategy to build two-component luminescent materials with emerged circularly polarized luminescence properties.A library of Fmoc-amino acids was built,which selectively form charge-transfer complexes with the electron-deficient acceptor.Embedding in amorphous polymer matrix or physical grinding could trigger the charge-transfer luminescence with ad-justed wavelengths in a general manner.X-ray diffraction results suggest the multiple binding modes be-tween donor and acceptor.And,the solution-processed coassembly could selectively exhibit circularly po-larized luminescence with high dissymmetry g-factors.This work illustrates a noncovalent charge-transfer strategy to construct luminescent and chiroptical organic composites based on the easy-accessible and economic chiral N-terminal aromatic amino acids.
文献关键词：
中图分类号：
作者姓名：
Yiran Xia;Aiyou Hao;Pengyao Xing
作者机构：
Key Laboratory of Colloid and Interface Chemistry of Ministry of Education and School of Chemistry and Chemical Engineering,Shandong University,Ji'nan 250100,China
文献出处：
引用格式：
[1]Yiran Xia;Aiyou Hao;Pengyao Xing-.Fmoc-protected amino acids as luminescent and circularly polarized luminescence materials based on charge transfer interaction)[J].中国化学快报（英文版）,2022(11):4918-4923
A类：
Fluorenylmethyloxycarbonyl,justed
B类：
Fmoc,protected,amino,acids,luminescent,circularly,polarized,luminescence,materials,charge,transfer,interaction,are,effective,building,blocks,self,assembled,architectures,hierarchical,levels,which,however,show,limited,properties,chiroptical,activities,Here,introduce,strategy,two,component,emerged,library,was,built,selectively,form,complexes,electron,deficient,acceptor,Embedding,amorphous,polymer,matrix,physical,grinding,could,trigger,ad,wavelengths,general,manner,ray,diffraction,results,suggest,multiple,binding,modes,tween,donor,And,solution,processed,coassembly,exhibit,high,dissymmetry,factors,This,work,illustrates,noncovalent,construct,organic,composites,easy,accessible,economic,chiral,terminal,aromatic
AB值：
0.587777
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