典型文献
Chemo-,site-selective reduction of nitroarenes under blue-light,catalyst-free conditions
文献摘要：
The tandem reaction of photoinduced double hydrogen-atom transfer and deoxygenative transborylation for chemo-and site-selective reduction of nitroarenes into aryl amines under catalyst-free,room temper-ature conditions was disclosed in excellent yields.In this reaction,isopropanol(1PrOH)was used as hy-drogen donor and tetrahydroxydiboron[B2(OH)4]as deoxygenative reagent with green,cheap,and com-mercially available credentials.In particular,a wide range of reducible functional groups such as halogen(-Cl,-Br and even-Ⅰ),alkenyl,alkynyl,aldehyde,ketone,carboxyl,and cyano are all tolerated.Moreover,the reaction preferentially reduces the nitro group at the electron-deficient site over another nitro group in the same molecule.A detailed mechanistic investigation in combination of experiments and theoretical calculations gave a reasonable explanation for the reaction pathway.
文献关键词：
中图分类号：
作者姓名：
Bin Wang;Jiawei Ma;Hongyuan Ren;Shuo Lu;Jingkai Xu;Yong Liang;Changsheng Lu;Hong Yan
作者机构：
State Key Laboratory of Coordination Chemistry,Jiangsu Key Laboratory of Advanced Organic Materials,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China
文献出处：
引用格式：
[1]Bin Wang;Jiawei Ma;Hongyuan Ren;Shuo Lu;Jingkai Xu;Yong Liang;Changsheng Lu;Hong Yan-.Chemo-,site-selective reduction of nitroarenes under blue-light,catalyst-free conditions)[J].中国化学快报（英文版）,2022(05):2420-2424
A类：
Chemo,deoxygenative,transborylation,1PrOH,tetrahydroxydiboron,credentials
B类：
site,selective,reduction,nitroarenes,under,blue,light,catalyst,free,conditions,tandem,reaction,photoinduced,double,hydrogen,atom,transfer,chemo,into,aryl,amines,room,temper,ature,was,disclosed,excellent,yields,In,this,isopropanol,used,donor,B2,reagent,green,cheap,mercially,available,particular,wide,range,reducible,functional,groups,such,halogen,Cl,Br,even,alkenyl,alkynyl,aldehyde,ketone,carboxyl,cyano,tolerated,Moreover,preferentially,reduces,electron,deficient,another,same,molecule,detailed,mechanistic,investigation,combination,experiments,theoretical,calculations,gave,reasonable,explanation,pathway
AB值：
0.623108
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