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典型文献
Evidence for a High-Pressure Isostructural Transition in Nitrogen
文献摘要:
We observed an isostructural phase transition in the solid nitrogen λ-N2 at approximately 50 GPa accompanied by anomalies in lattice parameters,atomic volume and Raman vibron modes.The anomalies are ascribed to a slight reorientation of the nitrogen molecules,which does not seem to affect the monoclinic symmetry (space group P21/c).Our ab initio calculations further confirm the phenomena,and suggest an optimized structure for the λ-N2 phase.In addition,a new high-pressure amorphous phase of η'-N2 was also discovered by a detailed investigation of the pressure-temperature phase diagram of nitrogen with the aim of probing the phase stability of λ-N2.Our result may provide helpful information about the crystallographic nature of dissociation transitions in diatomic molecular crystals (H2,O2,N2,etc).
文献关键词:
作者姓名:
Chunmei Fan;Shan Liu;Jingyi Liu;Binbin Wu;Qiqi Tang;Yu Tao;Meifang Pu;Feng Zhang;Jianfu Li;Xiaoli Wang;Duanwei He;Chunyin Zhou;Li Lei
作者机构:
Institute of Atomic and Molecular Physics,Sichuan University,Chengdu 610065,China;School of Opto-Electronic Information Science and Technology,Yantai University,Yantai 264005,China;Shanghai Synchrotron Radiation Facility,Shanghai Advanced Research Institute,Chinese Academy of Sciences,Shanghai 201204,China
引用格式:
[1]Chunmei Fan;Shan Liu;Jingyi Liu;Binbin Wu;Qiqi Tang;Yu Tao;Meifang Pu;Feng Zhang;Jianfu Li;Xiaoli Wang;Duanwei He;Chunyin Zhou;Li Lei-.Evidence for a High-Pressure Isostructural Transition in Nitrogen)[J].中国物理快报(英文版),2022(02):63-75
A类:
Isostructural,vibron
B类:
Evidence,High,Pressure,Transition,Nitrogen,We,observed,isostructural,phase,solid,nitrogen,N2,approximately,GPa,accompanied,by,anomalies,lattice,parameters,volume,Raman,modes,are,ascribed,slight,reorientation,molecules,which,does,not,seem,affect,monoclinic,symmetry,space,group,P21,Our,initio,calculations,further,confirm,phenomena,suggest,optimized,structure,In,addition,new,high,pressure,amorphous,was,also,discovered,detailed,investigation,temperature,diagram,aim,probing,stability,result,may,provide,helpful,information,about,crystallographic,nature,dissociation,transitions,diatomic,molecular,crystals,H2,O2,etc
AB值:
0.70492
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