Orientation control of anisotropic one-dimensional(1D)and two-dimensional(2D)materials in solutions is of great importance in many fields ranging from structural materials design,the thermal management,to energy storage.Achieving fine control of vertical alignment of anisotropic fillers(such as graphene,boron nitride(BN),and carbon fiber)remains challenging.This work presents a universal and scalable method for constructing vertically aligned structures of anisotropic fillers in composites assisted by the expansion flow(using 2D BN platelets as a proof-of-concept).BN platelets in the silicone gel strip are oriented in a curved shape that includes vertical alignment in the central area and horizontal alignment close to strip surfaces.Due to the vertical orientation of BN in the central area of strips,a through-plane thermal conductivity as high as 5.65 W m-1 K-1 was obtained,which can be further improved to 6.54 W m-1 K-1 by combining BN and pitch-based carbon fibers.The expansion-flow-assisted alignment can be extended to the manufacture of a variety of polymer composites filled with 1D and 2D materials,which can find wide applications in batteries,electronics,and energy storage devices.

Hongyu Niu;Haichang Guo;Lei Kang;Liucheng Ren;Ruicong Lv;Shulin Bai

School of Materials Science and Engineering,HEDPS/Center for Applied Physics and Technology,Key Laboratory of Polymer Chemistry and Physics of Ministry of Education,Peking University,Beijing 100871,People's Republic of China;Peking University Nanchang Innovation Institute,14#1-2 Floor,High-level Talent Industrial Park,High-Tech District,Nanchang City 330224,Jiangxi Province,People's Republic of China

纳微快报（英文）

[1]Hongyu Niu;Haichang Guo;Lei Kang;Liucheng Ren;Ruicong Lv;Shulin Bai-.Vertical Alignment of Anisotropic Fillers Assisted by Expansion Flow in Polymer Composites)[J].纳微快报（英文）,2022(09):257-271

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