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典型文献
Tuning the properties of Ni-based catalyst via La incorporation for efficient hydrogenation of petroleum resin
文献摘要:
The hydrogenation of petroleum resin(PR)is an effective process to prepare high value-added hydro-genated PR(HPR).However,the preparation of non-noble metal-based catalysts with high catalytic activ-ity for PR hydrogenation still remains a challenge.Herein,a La promoted Ni-based catalyst is reported through the thermal reduction of quaternary NiLaMgAl-layered double hydroxides(NiLaMgAl-LDHs).The incorporation of La is beneficial to the reduction and stability of Ni particles with reduced particle size,and the increased alkalinity effectively mitigates the breakage of molecular chains of PR.As a result,the La promoted Ni-based catalyst exhibits high catalytic activity and excellent stability for PR hydro-genation.A hydrogenation degree of 95.4%and 96.1%can be achieved for HC5PR and HC9PR with less reduced softening point,respectively.Notably,the hydrogenation degree still maintains at 92.7%even after 100 hours'reaction,much better than that without La incorporation or prepared using conventional impregnation method.
文献关键词:
作者姓名:
Qunhong Liu;Jiangtao Yang;Hongwei Zhang;Hongming Sun;Shuzheng Wu;Bingqing Ge;Rong Wang;Pei Yuan
作者机构:
Research Center of Chemical Fertilizer Catalyst,Fuzhou University,Fuzhou 350002,China;College of Chemical Engineering,Fuzhou University,Fuzhou 350116,China
引用格式:
[1]Qunhong Liu;Jiangtao Yang;Hongwei Zhang;Hongming Sun;Shuzheng Wu;Bingqing Ge;Rong Wang;Pei Yuan-.Tuning the properties of Ni-based catalyst via La incorporation for efficient hydrogenation of petroleum resin)[J].中国化学工程学报(英文版),2022(05):41-50
A类:
NiLaMgAl,HC5PR,HC9PR
B类:
Tuning,properties,via,incorporation,efficient,hydrogenation,petroleum,resin,is,process,high,value,added,genated,HPR,However,preparation,noble,metal,catalysts,catalytic,still,remains,challenge,Herein,promoted,reported,through,thermal,reduction,quaternary,layered,double,hydroxides,LDHs,beneficial,stability,particles,reduced,size,increased,alkalinity,effectively,mitigates,breakage,molecular,chains,result,exhibits,activity,excellent,degree,can,achieved,less,softening,point,respectively,Notably,maintains,even,after,hours,reaction,much,better,than,that,without,prepared,using,conventional,impregnation,method
AB值:
0.510574
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