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典型文献
Large-scale synthesis of polyynes with commercial laser marking technology
文献摘要:
The space-confined synthesis method has been an efficient way for the preparation of linear carbon chains.However,the large-scale preparation of linear carbon chains still faces many challenges due to the lack of methods for the large-scale synthesis of precursors,such as short carbon chains(polyynes),and regulation technology for the transport of reactants in one-dimensional space.Here,we report a facile method for the rapid preparation of polyynes in large quantities using a commercial laser marking machine.Spectroscopic characterizations show that a large number of polyynes,such as C8H2,C10H2,C12H2,and C14H2,can be produced by ablating the graphite plate immersed in the organic liquid using a laser marking machine.The results of in situ Raman spectroscopy investigation of C2nH2-filled single-walled carbon nanotubes further confirm that a variety of polyyne molecules are synthesized.Meanwhile,in situ Raman spectroscopy also shows that the local heating treatment can accelerate the filling process of C2nH2 into one-dimensional channels.This work provides new insights into the study of linear carbon chains and space-confined synthesis methods.
文献关键词:
作者姓名:
Liang Fang;Yanping Xie;Shujie Sun;Wei Zi
作者机构:
Collaborative Innovation Center of Henan Province for Energy-Saving Building Materials,Xinyang Normal University,Xinyang 464000,China;Analysis&Testing Center,Xinyang Normal University,Xinyang 464000,China
引用格式:
[1]Liang Fang;Yanping Xie;Shujie Sun;Wei Zi-.Large-scale synthesis of polyynes with commercial laser marking technology)[J].中国物理B(英文版),2022(12):194-197
A类:
polyynes,C8H2,C10H2,C12H2,C14H2,C2nH2,polyyne
B类:
Large,scale,synthesis,commercial,laser,marking,technology,space,confined,has,been,efficient,way,preparation,linear,carbon,chains,However,large,still,faces,many,challenges,due,lack,methods,precursors,such,short,regulation,transport,reactants,one,dimensional,Here,report,facile,rapid,quantities,using,machine,Spectroscopic,characterizations,that,number,can,produced,by,ablating,graphite,plate,immersed,organic,liquid,results,situ,Raman,spectroscopy,investigation,filled,single,walled,nanotubes,further,confirm,variety,molecules,are,synthesized,Meanwhile,also,shows,local,heating,treatment,accelerate,filling,process,into,channels,This,work,provides,new,insights,study
AB值:
0.497594
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