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典型文献
Effect of particle micro-structure on the electrochemical properties of LiNi0.8Co0.1Mn0.1O2 cathode material
文献摘要:
Ni-rich layered material is a kind of high-capacity cathode to meet the requirement of electric vehicles. As for the typical LiNi0.8Co0.1Mn0.1O2 material, the particle formation is significant for electrochemical properties of the cathode. In this work, the structure, mor-phology, and electrochemical performance of LiNi0.8Co0.1Mn0.1O2 secondary particles and single crystals were systematically studied. A lower Ni2+/Ni3+ molar ratio of 0.66 and a lower residual alkali content of 0.228wt% were achieved on the surface of the single crystals. In addition, the single crystals showed a discharge capacity of 191.6 mAh/g at 0.2 C (~12 mAh/g lower than that of the secondary particles) and enhanced the electrochemical stability, especially when cycled at 50°C and in a wider electrochemical window (between 3.0 and 4.4 V vs. Li+/Li). The LiNi0.8Co0.1Mn0.1O2 secondary particles were suitable for applications requiring high specific capacity, whereas single crystals exhibited better stability, indicating that they are more suitable for use in long life requested devices.
文献关键词:
作者姓名:
Zexun Tang;Hongqi Ye;Xin Ma;Kai Han
作者机构:
Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources,College of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China;Cathode Material Research&Development Department,Soundon New Energy Technology Co.Ltd.,Xiangtan 411100,China
引用格式:
[1]Zexun Tang;Hongqi Ye;Xin Ma;Kai Han-.Effect of particle micro-structure on the electrochemical properties of LiNi0.8Co0.1Mn0.1O2 cathode material)[J].矿物冶金与材料学报,2022(08):1618-1626
A类:
228wt
B类:
Effect,micro,structure,electrochemical,properties,LiNi0,8Co0,1Mn0,1O2,cathode,material,rich,layered,kind,high,capacity,meet,requirement,electric,vehicles,typical,formation,significant,In,this,work,phology,performance,secondary,particles,single,crystals,were,systematically,studied,lower,Ni2+,Ni3+,molar,ratio,residual,alkali,content,achieved,surface,addition,showed,discharge,mAh,than,that,enhanced,stability,especially,when,cycled,wider,window,between,Li+,suitable,applications,requiring,specific,whereas,exhibited,better,indicating,they,are,more,use,long,life,requested,devices
AB值:
0.503759
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